Efficient Conversion of Tomatidine into Neuritogenic Pregnane Derivative
نویسندگان
چکیده
منابع مشابه
Mechanism for conversion of spirosolane derivative into pregnane.
Previously, we reported an interesting reaction by which esculeogenin A [(5alpha,22S,23S,25S)-3beta,23,27-trihydroxyspirosolane], a sapogenol of tomato-saponin, esculeoside A, was easily converted into a pregnane derivative, 5alpha-pregn-16-en-3beta-ol-20-one, merely by refluxing with pyridine and water. Its chemical mechanism including air oxidation is here described.
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 2007
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.55.1077